Sascha Ott group

Alternating Metal-Ligand Coordination Improves Electrocatalytic CO₂ Reduction by a Mononuclear Ru Catalyst

Agarwala, Hemlata; Chen, Xiaoyu; Lyonnet, Julien R.; Johnson, Ben A. et al.

Part of Angewandte Chemie International Edition, 2023

• DOI for Alternating Metal-Ligand Coordination Improves Electrocatalytic CO₂ Reduction by a Mononuclear Ru Catalyst
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Mechanistic Insights and Synthetic Explorations of the Photoredox-Catalyzed Activation of Halophosphines

Arkhypchuk, Anna I.; Tran, Thuan T.; Charaf, Rima; Hammarström, Leif et al.

Part of Inorganic Chemistry, p. 18391-18398, 2023

• DOI for Mechanistic Insights and Synthetic Explorations of the Photoredox-Catalyzed Activation of Halophosphines
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Highly Conjugated Bis(benzo[b]phosphole)-P-oxides: Synthesis and Electrochemical, Optical, and Computational Studies

D'Imperio, Nicolas; Pelliccioli, Valentina; Grecchi, Sara; Bossi, Alberto et al.

Part of European Journal of Organic Chemistry, 2023

• DOI for Highly Conjugated Bis(benzo[b]phosphole)-P-oxides: Synthesis and Electrochemical, Optical, and Computational Studies
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Precursors for the Development of π-Conjugated Low-Coordinate Phosphorus Compounds

Esfandiarfard, Keyhan; Arkhypchuk, Anna I.; Orthaber, Andreas; Ott, Sascha

Part of ChemPlusChem, 2023

• DOI for Precursors for the Development of π-Conjugated Low-Coordinate Phosphorus Compounds
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The Influence of Water in the Vapor-Assisted Conversion Synthesis of UiO-67 MOF Thin Films

Gschwind, Wanja; McCarthy, Brian D.; Suremann, Nina F.; Ott, Sascha

Part of European Journal of Inorganic Chemistry, 2023

• DOI for The Influence of Water in the Vapor-Assisted Conversion Synthesis of UiO-67 MOF Thin Films
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Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency

Kumar, Amol; Li, Jingguo; Inge, A. Ken; Ott, Sascha

Part of ACS Nano, p. 21595-21603, 2023

• DOI for Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency
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Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching

Li, Jingguo; Kumar, Amol; Johnson, Ben A.; Ott, Sascha

Part of Nature Communications, 2023

• DOI for Experimental manifestation of redox-conductivity in metal-organic frameworks and its implication for semiconductor/insulator switching
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Visible-light photoredox catalysis with organic polymers

Pandey, Gaurav Kumar; Cai, Bin; Ott, Sascha; Tian, Haining

Part of CHEMICAL PHYSICS REVIEWS, 2023

• DOI for Visible-light photoredox catalysis with organic polymers
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Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

Suremann, Nina F.; McCarthy, Brian D.; Gschwind, Wanja; Kumar, Amol et al.

Part of Chemical Reviews, p. 6545-6611, 2023

• DOI for Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
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Lateral Electron and Hole Hopping between Dyes on Mesoporous ZrO₂: Unexpected Influence of Solvents with a Low Dielectric Constant

Wrede, Sina; Cai, Bin; Kumar, Amol; Ott, Sascha et al.

Part of Journal of the American Chemical Society, p. 11472-11476, 2023

• DOI for Lateral Electron and Hole Hopping between Dyes on Mesoporous ZrO₂: Unexpected Influence of Solvents with a Low Dielectric Constant
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Hydroxyl-Decorated Diiron Complex as a [FeFe]-Hydrogenase Active Site Model Complex: Light-Driven Photocatalytic Activity and Heterogenization on Ethylene-Bridged Periodic Mesoporous Organosilica

Amaro-Gahete, Juan; Esquivel, Dolores; Pavliuk, Mariia V.; Jimenez-Sanchidrian, Cesar et al.

Part of Catalysts, 2022

• DOI for Hydroxyl-Decorated Diiron Complex as a [FeFe]-Hydrogenase Active Site Model Complex: Light-Driven Photocatalytic Activity and Heterogenization on Ethylene-Bridged Periodic Mesoporous Organosilica
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[2+2] Cycloaddition of phosphaalkenes as a key step for the reductive coupling of diaryl ketones to tetraaryl olefins

Arkhypchuk, Anna I.; D'Imperio, Nicolas; Wells, Jordann A. L.; Ott, Sascha

Part of Chemical Science, p. 12239-12244, 2022

• DOI for [2+2] Cycloaddition of phosphaalkenes as a key step for the reductive coupling of diaryl ketones to tetraaryl olefins
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Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal-Organic Framework

Castner, Ashleigh T.; Su, Hao; Grape, Erik Svensson; Inge, A. Ken et al.

Part of Journal of the American Chemical Society, p. 5910-5920, 2022

• DOI for Microscopic Insights into Cation-Coupled Electron Hopping Transport in a Metal-Organic Framework
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Electrocatalytic water oxidation from a mixed linker MOF based on NU-1000 with an integrated ruthenium-based metallo-linker

Howe, Andrew; Liseev, Timofey; Gil-Sepulcre, Marcos; Gimbert-Suriñach, Carolina et al.

Part of Materials Advances, p. 4227-4234, 2022

• DOI for Electrocatalytic water oxidation from a mixed linker MOF based on NU-1000 with an integrated ruthenium-based metallo-linker
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Gold nanoparticle-based supramolecular approach for dye-sensitized H-2-evolving photocathodes

Lalaoui, Noemie; Abdellah, Mohamed; Materna, Kelly L.; Xu, Bo et al.

Part of Dalton Transactions, p. 15716-15724, 2022

• DOI for Gold nanoparticle-based supramolecular approach for dye-sensitized H-2-evolving photocathodes
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Z-Selective Alkene Formation from Reductive Aldehyde Homo-Couplings

Mai, Juri; Arkhypchuk, Anna I.; Wagner, Sebastian; Orthaber, Andreas et al.

Part of European Journal of Organic Chemistry, 2022

• DOI for Z-Selective Alkene Formation from Reductive Aldehyde Homo-Couplings
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Two routes to hydrogen evolution for a Co-polypyridyl complex with two open sites

Toro, Liqin Xue; Kiriakidi, Sofia; Thapper, Anders; Ott, Sascha et al.

Part of Electronic Structure, 2022

• DOI for Two routes to hydrogen evolution for a Co-polypyridyl complex with two open sites
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Catalytic systems mimicking the [FeFe]-hydrogenase active site for visible-light-driven hydrogen production

Amaro-Gahete, Juan; Pavliuk, Mariia V.; Tian, Haining; Esquivel, Dolores et al.

Part of Coordination chemistry reviews, 2021

• DOI for Catalytic systems mimicking the [FeFe]-hydrogenase active site for visible-light-driven hydrogen production
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Mimicking the Electron Transport Chain and Active Site of [FeFe] Hydrogenases in One Metal-Organic Framework: Factors That Influence Charge Transport

Castner, Ashleigh T.; Johnson, Ben A.; Cohen, Seth M.; Ott, Sascha

Part of Journal of the American Chemical Society, p. 7991-7999, 2021

• DOI for Mimicking the Electron Transport Chain and Active Site of [FeFe] Hydrogenases in One Metal-Organic Framework: Factors That Influence Charge Transport
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Ultrafast Dynamics in Cu-Deficient CuInS2 Quantum Dots: Sub-Bandgap Transitions and Self-Assembled Molecular Catalysts

Eliasson, Nora; Pettersson-Rimgard, Belinda; Castner, Ashleigh T.; Tai, Cheuk-Wai et al.

Part of The Journal of Physical Chemistry C, p. 14751-14764, 2021

• DOI for Ultrafast Dynamics in Cu-Deficient CuInS2 Quantum Dots: Sub-Bandgap Transitions and Self-Assembled Molecular Catalysts
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Immobilising molecular Ru complexes on a protective ultrathin oxide layer of p-Si electrodes towards photoelectrochemical CO2 reduction

Laurans, Maxime; Wells, Jordann A. L.; Ott, Sascha

Part of Dalton Transactions, p. 10482-10492, 2021

• DOI for Immobilising molecular Ru complexes on a protective ultrathin oxide layer of p-Si electrodes towards photoelectrochemical CO2 reduction
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Elemental Depth Profiling of Intact Metal-Organic Framework Single Crystals by Scanning Nuclear Microprobe

McCarthy, Brian D.; Liseev, Timofey; Sortica, Mauricio A.; Paneta, Valentina et al.

Part of Journal of the American Chemical Society, p. 18626-18634, 2021

• DOI for Elemental Depth Profiling of Intact Metal-Organic Framework Single Crystals by Scanning Nuclear Microprobe
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Electrochemical, Spectroscopic, and Computational Investigation of a Series of Polypyridyl Ruthenium(II) Complexes: Characterization of Reduced States

Queyriaux, Nicolas; Esmieu, Charlène; Gupta, Arvind Kumar; Vendier, Laure et al.

Part of European Journal of Inorganic Chemistry, p. 1263-1270, 2021

• DOI for Electrochemical, Spectroscopic, and Computational Investigation of a Series of Polypyridyl Ruthenium(II) Complexes: Characterization of Reduced States

Photoinduced Fano Resonances between Quantum Confined Nanocrystals and Adsorbed Molecular Catalysts

Yang, Wenxing; Liu, Yawei; Edvinsson, Tomas; Castner, Ashleigh T. et al.

Part of Nano Letters, p. 5813-5818, 2021

• DOI for Photoinduced Fano Resonances between Quantum Confined Nanocrystals and Adsorbed Molecular Catalysts

Enhancing photovoltages at p-type semiconductors through a redox-active metal-organic framework surface coating

Beiler, Anna M.; McCarthy, Brian D.; Johnson, Ben A.; Ott, Sascha

Part of Nature Communications, 2020

• DOI for Enhancing photovoltages at p-type semiconductors through a redox-active metal-organic framework surface coating
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Self-Recovery of Photochemical H₂ Evolution with a Molecular Diiron Catalyst Incorporated in a UiO-66 Metal-Organic Framework

Bozal-Ginesta, Carlota; Pullen, Sonja; Ott, Sascha; Hammarström, Leif

Part of ChemPhotoChem, p. 287-290, 2020

• DOI for Self-Recovery of Photochemical H₂ Evolution with a Molecular Diiron Catalyst Incorporated in a UiO-66 Metal-Organic Framework

E,Z-Selectivity in the reductive cross-coupling of two benzaldehydes to stilbenes under substrate control

D'Imperio, Nicolas; Ott, Sascha; Arkhypchuk, Anna I.

Part of Organic & Biomolecular chemistry, p. 6171-6179, 2020

• DOI for E,Z-Selectivity in the reductive cross-coupling of two benzaldehydes to stilbenes under substrate control
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Transport Phenomena: Challenges and Opportunities for Molecular Catalysis in Metal-Organic Frameworks

Johnson, Ben A.; Beiler, Anna M.; McCarthy, Brian D.; Ott, Sascha

Part of Journal of the American Chemical Society, p. 11941-11956, 2020

• DOI for Transport Phenomena: Challenges and Opportunities for Molecular Catalysis in Metal-Organic Frameworks
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Diagnosing surface versus bulk reactivity for molecular catalysis within metal-organic frameworks using a quantitative kinetic model

Johnson, Ben A.; Ott, Sascha

Part of Chemical Science, p. 7468-7478, 2020

• DOI for Diagnosing surface versus bulk reactivity for molecular catalysis within metal-organic frameworks using a quantitative kinetic model
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Synthetic strategies to incorporate Ru-terpyridyl water oxidation catalysts into MOFs: direct synthesis vs. post-synthetic approach

Liseev, Timofey; Howe, Andrew; Hoque, Md Asmaul; Gimbert-Surinach, Carolina et al.

Part of Dalton Transactions, p. 13753-13759, 2020

• DOI for Synthetic strategies to incorporate Ru-terpyridyl water oxidation catalysts into MOFs: direct synthesis vs. post-synthetic approach

Understanding the Performance of NiO Photocathodes with Alkyl-Derivatized Cobalt Catalysts and a Push-Pull Dye

Materna, Kelly L.; Beiler, Anna M.; Thapper, Anders; Ott, Sascha et al.

Part of ACS Applied Materials and Interfaces, p. 31372-31381, 2020

• DOI for Understanding the Performance of NiO Photocathodes with Alkyl-Derivatized Cobalt Catalysts and a Push-Pull Dye
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Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

Materna, Kelly L.; Lalaoui, Noémie; Laureanti, Joseph A.; Walsh, Aaron P. et al.

Part of ACS Applied Materials and Interfaces, p. 4501-4509, 2020

• DOI for Using Surface Amide Couplings to Assemble Photocathodes for Solar Fuel Production Applications

Analysis of electrocatalytic metal-organic frameworks

McCarthy, Brian D.; Beiler, Anna M.; Johnson, Ben A.; Liseev, Timofey et al.

Part of Coordination chemistry reviews, 2020

• DOI for Analysis of electrocatalytic metal-organic frameworks

Triarylalkenes from the site-selective reductive cross-coupling of benzophenones and aldehydes

Arkhypchuk, Anna I.; D'Imperio, Nicolas; Ott, Sascha

Part of Chemical Communications, p. 6030-6033, 2019

• DOI for Triarylalkenes from the site-selective reductive cross-coupling of benzophenones and aldehydes
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Synthesis and properties of a heterobimetallic iron-manganese complex and its comparison with homobimetallic analogues

Bedin, Michele; Agarwala, Hemlata; Marx, Jennifer; Schünemann, Volker et al.

Part of Inorganica Chimica Acta, p. 254-260, 2019

• DOI for Synthesis and properties of a heterobimetallic iron-manganese complex and its comparison with homobimetallic analogues

Structural features of molecular electrocatalysts in multi-electron redox processes for renewable energy: recent advances

Das, Biswanath; Thapper, Anders; Ott, Sascha; Colbran, Stephen B.

Part of Sustainable Energy & Fuels, p. 2159-2175, 2019

• DOI for Structural features of molecular electrocatalysts in multi-electron redox processes for renewable energy: recent advances

Triphenylphosphaalkenes in Chemical Equilibria

D'Imperio, Nicolas; Arkhypchuk, Anna I.; Mai, Juri; Ott, Sascha

Part of European Journal of Inorganic Chemistry, p. 1562-1566, 2019

• DOI for Triphenylphosphaalkenes in Chemical Equilibria

Post synthetic exchange enables orthogonal click chemistry in a metal organic framework

Fluch, Ulrike; McCarthy, Brian D.; Ott, Sascha

Part of Dalton Transactions, p. 45-49, 2019

• DOI for Post synthetic exchange enables orthogonal click chemistry in a metal organic framework

Elucidating Proton-Coupled Electron Transfer Mechanisms of Metal Hydrides with Free Energy- and Pressure-Dependent Kinetics

Liu, Tianfei; Tyburski, Robin; Wang, Shihuai; Fernandez-Teran, Ricardo et al.

Part of Journal of the American Chemical Society, p. 17245-17259, 2019

• DOI for Elucidating Proton-Coupled Electron Transfer Mechanisms of Metal Hydrides with Free Energy- and Pressure-Dependent Kinetics

The Fascinating World of Phosphanylphosphonates: From Acetylenic Phosphaalkenes to Reductive Aldehyde Couplings

Mai, Juri; Ott, Sascha

Part of Synlett, p. 1867-1885, 2019

• DOI for The Fascinating World of Phosphanylphosphonates: From Acetylenic Phosphaalkenes to Reductive Aldehyde Couplings

Facile Orientational Control of M2L2P SURMOFs on < 100 > Silicon Substrates and Growth Mechanism Insights for Defective MOFs

McCarthy, Brian D.; Liseev, Timofey; Beiler, Anna M.; Materna, Kelly L. et al.

Part of ACS Applied Materials and Interfaces, p. 38294-38302, 2019

• DOI for Facile Orientational Control of M2L2P SURMOFs on < 100 > Silicon Substrates and Growth Mechanism Insights for Defective MOFs

Restricted rotation of an Fe(CO)(2)(PL3)-subunit in [FeFe]-hydrogenase active site mimics by intramolecular ligation

Pullen, Sonja; Maji, Somnath; Stein, Matthias; Ott, Sascha

Part of Dalton Transactions, p. 5933-5939, 2019

• DOI for Restricted rotation of an Fe(CO)(2)(PL3)-subunit in [FeFe]-hydrogenase active site mimics by intramolecular ligation
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Mechanistic insights on the non-innocent role of electron donors: reversible photocapture of CO2 by Ru-II-polypyridyl complexes

Queyriaux, Nicolas; Swords, Wesley B.; Agarwata, Hemtata; Johnson, Ben A. et al.

Part of Dalton Transactions, p. 16894-16898, 2019

• DOI for Mechanistic insights on the non-innocent role of electron donors: reversible photocapture of CO2 by Ru-II-polypyridyl complexes

Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film

Roy, Souvik; Huang, Zhehao; Bhunia, Asamanjoy; Castner, Ashleigh et al.

Part of Journal of the American Chemical Society, p. 15942-15950, 2019

• DOI for Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal-Organic Framework Thin Film

Direct Spectroscopic Detection of Key Intermediates and Turnover Process in Catalytic H₂ Formation by a Biomimetic Diiron Catalyst

Wang, Shihuai; Pullen, Sonja; Weippert, Valentin; Liu, Tianfei et al.

Part of Chemistry - A European Journal, p. 11135-11140, 2019

• DOI for Direct Spectroscopic Detection of Key Intermediates and Turnover Process in Catalytic H₂ Formation by a Biomimetic Diiron Catalyst

One-Pot Intermolecular Reductive Cross-Coupling of Deactivated Aldehydes to Unsymmetrically 1,2-Disubstituted Alkenes

Arkhypchuk, Anna I.; D'Imperio, Nicolas; Ott, Sascha

Part of Organic Letters, p. 5086-5089, 2018

• DOI for One-Pot Intermolecular Reductive Cross-Coupling of Deactivated Aldehydes to Unsymmetrically 1,2-Disubstituted Alkenes

Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration

Bhunia, Asamanjoy; Johnson, Ben A.; Czapla-Masztafiak, Joanna; Sá, Jacinto et al.

Part of Chemical Communications, p. 7770-7773, 2018

• DOI for Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration
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Self-quenching and Slow Hole Injection May Limit the Efficiency in NiO-based Dye-Sensitized Solar Cells

Föhlinger, Jens; Maji, Somnath; Brown, Allison M.; Mijangos, Edgar et al.

Part of The Journal of Physical Chemistry C, p. 13902-13910, 2018

• DOI for Self-quenching and Slow Hole Injection May Limit the Efficiency in NiO-based Dye-Sensitized Solar Cells

Direct evidence of catalyst reduction on dye and catalyst co-sensitized NiO photocathodes by mid-infrared transient absorption spectroscopy

Gilbert Gatty, Mélina; Pullen, Sonja; Sheibani, E.; Tian, Haining et al.

Part of Chemical Science, p. 4983-4991, 2018

• DOI for Direct evidence of catalyst reduction on dye and catalyst co-sensitized NiO photocathodes by mid-infrared transient absorption spectroscopy
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Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers

Johnson, Ben A.; Bhunia, Asamanjoy; Fei, Honghan; Cohen, Seth M. et al.

Part of Journal of the American Chemical Society, p. 2985-2994, 2018

• DOI for Development of a UiO-Type Thin Film Electrocatalysis Platform with Redox-Active Linkers